PCC or Pyridinium chlorochromate|Organic Reagents|Biswajit Das

Organic Reagents|Biswajit Das

image 2 ALL ABOUT CHEMISTRY

In chemistry, PCC stands for Pyridinium Chlorochromate. It is a mild oxidizing agent used primarily in organic chemistry.

Full Form:

PCC = Pyridinium Chlorochromate


Chemical Formula:

Cโ‚…Hโ‚…NHโบCrOโ‚ƒClโป

It is usually a yellow-orange crystalline solid.


Common Use:

PCC is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones, without overoxidizing aldehydes to carboxylic acids.


Key Reaction:

R-CH2OH  +  PCC  โ†’  R-CHO
R2CHOH  +  PCC  โ†’  R2C=O

Example:

Ethanol to Acetaldehyde

CH3CH2OH + PCC โ†’ CH3CHO + H2O

Why use PCC?

  • It is selective and does not use water, so overoxidation to carboxylic acids is avoided.
  • Preferred in anhydrous conditions.


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